Diffraction grating
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For a given optical bench and array detector, the diffraction
grating can be selected to provide additional flexibility on
spectral coverage, spectral resolution, and etc. of the
spectrometer. The three important parameters that determine the
dispersion property of a diffraction grating include groove density
(g), grating width (Wg), and blaze wavelength (lB).
Based on the grating equation, the angular dispersion of a
diffraction grating can be expressed as:
db/dl
= 10-6×k×g/cos(b) (Equation 4-1)
where db/dl
is the angular dispersion in rad/nm; g is the groove density in
grooves/mm;
b
is the diffraction angle in rad; k is the diffraction order. For a
given optical bench, the linear dispersion will be:
dl/dx
= 106×
cos(b)/(k×g×F) (Equation 4-2)
where dl/dx
is the linear dispersion in nm/mm; F is the focal length of the
focusing mirror in mm (see Figure 4-1).
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When the spectral coverage range (Dl)
and the detector width, Wd (detector width) = n (pixel
number) * Wp (pixel width), are determined based on the
design specifications, the required linear dispersion of the optical
bench can be estimated as:
dl/dx
=
Dl/Wd
(Equation 4-3)
Thus the groove density (g) of the diffraction grating and the focal
length (F) of the optical bench can be designed according to
equations 4-2 and 4-3.
It should be noted that the longest wavelength that will be
diffracted by a grating is 2×d,
where d is the period of the grating, d = 1/g. This places a long
wavelength limit on the spectral range of the grating. For NIR
applications, this long wavelength limit may restrict the
maximum allowed groove density for the grating.
The minimum wavelength difference that can be resolved by the
diffraction grating is given by:
dl
=
l/(k×g×Wg)
=
l/(k×N)
where N is the total number of grooves on the diffraction grating.
Generally, the resolving power of the grating is much higher than
the spectral resolution requirement of the spectrometer (dl
<<
dl),
where
dl
is set by the pixel number of the array detector (see
equation 3-1).
When the required wavelength coverage is broad, i.e.
lmax
> 2×lmin,
optical signals in wavelengths from different diffraction orders may
end up at the same spatial position on the detector plane which can
be evident from the described grating equation. In this case, a
linear variable filter (LVF) option is provided for the spectrometer
in light path to filter out the unwanted order contributions, or
perform “order sorting”.
As we discussed before, there are two types of diffraction gratings,
i.e. ruled and holographic gratings. The ruled grating exhibits much
more stray light due to surface imperfections and other errors in
the groove period. Thus
for spectroscopic applications (such as UV spectroscopy) where the
detector response is poorer and optics are suffering more loss,
holographic gratings are generally selected to improve the stray
light performance of the spectrometer.
Gratings can be blazed to provide high diffraction efficiency (>85%)
at a specific wavelength, i.e. a blaze wavelength (lB).
As a rule of thumb, the grating efficiency will decrease by 50% at
0.6×lB
and 1.8×lB.
This sets a limit on the spectral coverage of the
spectrometer. Generally, the blaze wavelength of the diffraction
grating is biased toward the weak side of the spectral range to
improve the overall SNR of the spectrometer.
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